|
|
(4S,6S,7R,8S)-7,10-dihydroxy-8-(hydroxymethyl)-2,5-diazatricyclo[7.4.0.04,6]trideca-1(9),10,12-triene-12-carboxy-[acp] + H2O <=> 9beta-mitosane_core + [acyl-carrier_protein]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20321
|
|
|
|
(4S,6S,7R,8S)-7,10-dihydroxy-8-(hydroxymethyl)-2,5-diazatricyclo[7.4.0.04,6]trideca-1(9),10,12-triene-12-carboxy-[acp] + H2O <=> 9alpha-mitosane_core + [acyl-carrier_protein]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20323
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + [acyl-carrier_protein] <=> 3-amino-5-hydroxybenzoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20315
|
|
|
|
UDP-D-glucosamine + 3-amino-5-hydroxybenzoyl-[acyl-carrier_protein] <=> N-glucosaminyl-3-amino-5-hydroxybenzoyl-[acyl-carrier_protein] + UDP + H+
|
2.4.1
|
–
|
| |
MetaCyc:
RXN-20316
|
|
|
|
9alpha-mitosane_core + Carbamoyl_phosphate <=> carbamoylated_9alpha-mitosane_core + phosphate
|
2.1.3
|
–
|
| |
MetaCyc:
RXN-20324
|
|
|
|
S-adenosyl-L-methionine + 6-demethylmitomycin_A <=> S-adenosyl-L-homocysteine + mitomycin_A
|
2.1.1.316
mitomycin 6-O-methyltransferase
|
–
|
| |
BRENDA:
BR51219;
BS451818
KEGG:
R11191
MetaCyc:
RXN-16271
|
|
|
|
S-adenosyl-L-methionine + 7-demethylmitomycin_B <=> S-adenosyl-L-homocysteine + mitomycin_B
|
2.1.1.316
mitomycin 6-O-methyltransferase
|
–
|
| |
BRENDA:
BR51220
KEGG:
R11192
MetaCyc:
RXN-16272
|
|
|
|
carbamoylated_9alpha-mitosane_core <=> 7-demethylmitomycin_B
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20326
|
|
|
|
mitomycin_A <=> mitomycin_C
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20325
|
|
|
|
9beta-mitosane_core + Carbamoyl_phosphate <=> carbamoylated_9beta-mitosane_core + phosphate
|
2.1.3
|
–
|
| |
MetaCyc:
RXN-20322
|
|
|
|
3-{[(2S,3S,4S,5R)-2-amino-3,4,6-trihydroxy-5-phosphohexyl]amino}-5-hydroxybenzoyl-[acp] <=> (4S,6S,7R,8S)-7,10-dihydroxy-8-(hydroxymethyl)-2,5-diazatricyclo[7.4.0.04,6]trideca-1(9),10,12-triene-12-carboxy-[acp] + phosphate + H2O + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20319
|
|
|
|
carbamoylated_9beta-mitosane_core <=> 6-demethylmitomycin_A
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20320
|
|
|
|
N-glucosaminyl-3-amino-5-hydroxybenzoyl-[acyl-carrier_protein] + reduced_acceptor <=> 3-{[(2S,3S,4S,5R)-2-amino-3,4,5,6-tetrahydroxyhexyl]amino}-5-hydroxybenzoyl-[acp] + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20317
|
|
|
|
ATP + 3-{[(2S,3S,4S,5R)-2-amino-3,4,5,6-tetrahydroxyhexyl]amino}-5-hydroxybenzoyl-[acp] <=> 3-{[(2S,3S,4S,5R)-2-amino-3,4,6-trihydroxy-5-phosphohexyl]amino}-5-hydroxybenzoyl-[acp] + ADP + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20318
|
|
